Synthesis, crystal structure and properties of a 1D cadmium(II) coordination polymer with 2,6-dimethyl-3,5-bis(prazo-3-yl)pyridine

Fan, WenTao ; Zhu, Han ; Xu, QuanQing ; Kou, Jun Feng ; Liu, FengYi

Abstract

A new coordination polymer {[Cd(H2dmbpzp)I2]⋅CH3CH2OH}n (H2dmbpzp = 2,6-dimethyl-3,5-bis(prazo-3-y)pyridine) has been  prepared  by the reaction of H2dmbpzp in aqueous ethanolic solution at room temperature with CdI2. The compound was characterized by elemental analysis, IR spectroscopy, photoluminescence properties, thermogravimetric analysis (TGA) and single crystal X-ray diffraction. The complex exhibits a 1D chain structure.


Keyword(s)

synthesis, crystal structure, cadmium coordination polymer,  2,6-dimethyl-3,5-bis(prazo-3-yl)pyridine.


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